Building aqueous K-ion batteries for energy storage (2024)

1. Yang, Z. et al. Electrochemical energy storage for green grid. Chem. Rev. 111, 3577–3613 (2011).

   Article Google Scholar

2. Dunn, B., Kamath, H. & Tarascon, J.-M. Electrical energy storage for the grid: a battery of choices. Science 334, 928–935 (2011).

   Article Google Scholar

3. Kim, H. et al. Aqueous rechargeable Li and Na ion batteries. Chem. Rev. 114, 11788–11827 (2014).

   Article Google Scholar

4. Eftekhari, A., Jian, Z. & Ji, X. Potassium secondary batteries. ACS Appl. Mater. Interfaces 9, 4404–4419 (2017).

   Article Google Scholar

5. Kim, H. et al. Recent progress and perspective in electrode materials for K-ion batteries. Adv. Energy Mater. 8, 1702384 (2018).

   Article Google Scholar

6. Kubota, K., Dahbi, M., Hosaka, T., Kumakura, S. & Komaba, S. Towards K-ion and Na-ion batteries as “beyond Li-ion”. Chem. Rec. 18, 459–479 (2018).

   Article Google Scholar

7. Qian, J. et al. Prussian blue cathode materials for sodium-ion batteries and other ion batteries. Adv. Energy Mater. 8, 1702619 (2018).

   Article Google Scholar

8. Wessells, C. D., Peddada, S. V., Huggins, R. A. & Cui, Y. Nickel hexacyanoferrate nanoparticle electrodes for aqueous sodium and potassium ion batteries. Nano Lett. 11, 5421–5425 (2011).

   Article Google Scholar

9. Wessells, C. D., Huggins, R. A. & Cui, Y. Copper hexacyanoferrate battery electrodes with long cycle life and high power. Nat. Commun. 2, 550 (2011).

   Article Google Scholar

10. Su, D., McDonagh, A., Qiao, S. Z. & Wang, G. High-capacity aqueous potassium-ion batteries for large-scale energy storage. Adv. Mater. 29, 1604007 (2017).

    Article Google Scholar

11. Suo, L. et al. “Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries. Science 350, 938–943 (2015).

    Article Google Scholar

12. Leonard, D. P., Wei, Z., Chen, G., Du, F. & Ji, X. Water-in-salt electrolyte for potassium-ion batteries. ACS Energy Lett. 3, 373–374 (2018).

    Article Google Scholar

13. Liu, Y., Wei, G., Ma, M. & Qiao, Y. Role of acid in tailoring prussian blue as cathode for high-performance sodium-ion battery. Chem 23, 15991–15996 (2017).

    Article Google Scholar

14. Wu, X. et al. Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries. Nat. Energy 4, 123–130 (2019).

    Article Google Scholar

15. Ren, W., Chen, X. & Zhao, C. Ultrafast aqueous potassium-ion batteries cathode for stable intermittent grid-scale energy storage. Adv. Energy Mater. 8, 1801413 (2018).

    Article Google Scholar

16. Nakamoto, K., Sakamoto, R., Ito, M., Kitajou, A. & Okada, S. Effect of concentrated electrolyte on aqueous sodium-ion battery with sodium manganese hexacyanoferrate cathode. Electrochemistry 85, 179–185 (2017).

    Article Google Scholar

17. Wu, X. et al. Vacancy-free prussian blue nanocrystals with high capacity and superior cyclability for aqueous sodium-ion batteries. ChemNanoMat 1, 188–193 (2015).

    Article Google Scholar

18. Wu, X. Y. et al. Energetic aqueous rechargeable sodium-ion battery based on Na₂CuFe(CN)₆-NaTi₂(PO₄)₃ intercalation chemistry. ChemSusChem 7, 407–411 (2014).

    Article Google Scholar

19. Wu, X., Cao, Y., Ai, X., Qian, J. & Yang, H. A low-cost and environmentally benign aqueous rechargeable sodium-ion battery based on NaTi₂(PO₄)₃–Na₂NiFe(CN)₆ intercalation chemistry. Electrochem. Commun. 31, 145–148 (2013).

    Article Google Scholar

20. Wu, X. Y. et al. Low-defect Prussian blue nanocubes as high capacity and long life cathodes for aqueous Na-ion batteries. Nano Energy 13, 117–123 (2015).

    Article Google Scholar

21. Bie, X., Kubota, K., Hosaka, T., Chihara, K. & Komaba, S. A novel K-ion battery: hexacyanoferrate(II)/graphite cell. J. Mater. Chem. A 5, 4325–4330 (2017).

    Article Google Scholar

22. Xue, L. et al. Low-cost high-energy potassium cathode. J. Am. Chem. Soc. 139, 2164–2167 (2017).

    Article Google Scholar

23. Moritomo, Y., Urase, S. & Shibata, T. Enhanced battery performance in manganese hexacyanoferrate by partial substitution. Electrochim. Acta 210, 963–969 (2016).

    Article Google Scholar

24. Wu, X. et al. Rocking-chair ammonium-ion battery: a highly reversible aqueous energy storage system. Angew. Chem. Int. Ed. 56, 13026–13030 (2017).

    Article Google Scholar

25. Yamada, Y. et al. Hydrate-melt electrolytes for high-energy-density aqueous batteries. Nat. Energy 1, 16129 (2016).

    Article Google Scholar

26. Lukatskaya, M. R. et al. Concentrated mixed cation acetate “water-in-salt” solutions as green and low-cost high voltage electrolytes for aqueous batteries. Energy Environ. Sci. 11, 2876–2883 (2018).

    Article Google Scholar

27. Suo, L. et al. Advanced high-voltage aqueous lithium-ion battery enabled by “water-in-bisalt” electrolyte. Angew. Chem. Int. Ed. 55, 7136–7141 (2016).

    Article Google Scholar

28. Nakamoto, K., . & Sakamoto, R. & Sawada, Y. & Ito, M. & Okada, S. Over 2 V aqueous sodium-ion battery with prussian blue-type electrodes. Small Methods 3, 1800220 (2019).

    Article Google Scholar

29. Suo, L. et al. “Water-in-salt” electrolyte makes aqueous sodium-ion battery safe, green, and long-lasting. Adv. Energy Mater. 7, 1701189 (2017).

    Article Google Scholar

30. Gao, H. & Goodenough, J. B. An aqueous symmetric sodium-ion battery with NASICON-structured Na₃MnTi(PO₄)₃. Angew. Chem. Int. Ed. 55, 12768–12772 (2016).

    Article Google Scholar

31. Hou, Z., Li, X., Liang, J., Zhu, Y. & Qian, Y. An aqueous rechargeable sodium ion battery based on a NaMnO₂–NaTi₂(PO₄)₃ hybrid system for stationary energy storage. J. Mater. Chem. A 3, 1400–1404 (2015).

    Article Google Scholar

32. Fernández-Ropero, A. J., Saurel, D., Acebedo, B., Rojo, T. & Casas-Cabanas, M. Electrochemical characterization of NaFePO₄ as positive electrode in aqueous sodium-ion batteries. J. Power Sources 291, 40–45 (2015).

    Article Google Scholar

33. Pasta, M. et al. Full open-framework batteries for stationary energy storage. Nat. Commun. 5, 3007 (2014).

    Article Google Scholar

34. Kumar, D., Rajouria, S. K., Kuhar, S. B. & Kanchan, D. K. Progress and prospects of sodium-sulfur batteries: a review. Solid State Ion. 312, 8–16 (2017).

    Article Google Scholar

35. Hesse, H., Schimpe, M., Kucevic, D. & Jossen, A. Lithium-ion battery storage for the grid—a review of stationary battery storage system design tailored for applications in modern power grids. Energies 10, 2107 (2017).

    Article Google Scholar

36. Opiyo, N. Energy storage systems for PV-based communal grids. J. Energy Storage 7, 1–12 (2016).

    Article Google Scholar

37. Hueso, K. B., Armand, M. & Rojo, T. High temperature sodium batteries: status, challenges and future trends. Energy Environ. Sci. 6, 734 (2013).

    Article Google Scholar

38. Díaz-González, F., Sumper, A., Gomis-Bellmunt, O. & Villafáfila-Robles, R. A review of energy storage technologies for wind power applications. Renew. Sustain. Energy Rev. 16, 2154–2171 (2012).

    Article Google Scholar

39. Soloveichik, G. L. Battery technologies for large-scale stationary energy storage. Annu. Rev. Chem. Biomol. Eng. 2, 503–527 (2011).

    Article Google Scholar

40. Fetcenko, M. A. et al. Recent advances in NiMH battery technology. J. Power Sources 165, 544–551 (2007).

    Article Google Scholar

41. Yabuuchi, N., Kubota, K., Dahbi, M. & Komaba, S. Research development on sodium-ion batteries. Chem. Rev. 114, 11636–11682 (2014).

    Article Google Scholar

42. Pan, H. L., Hu, Y. S. & Chen, L. Q. Room-temperature stationary sodium-ion batteries for large-scale electric energy storage. Energy Environ. Sci. 6, 2338–2360 (2013).

    Article Google Scholar

43. Liang, Y. et al. Universal quinone electrodes for long cycle life aqueous rechargeable batteries. Nat. Mater. 16, 841–848 (2017).

    Article Google Scholar

44. Lee, M. et al. High-performance sodium–organic battery by realizing four-sodium storage in disodium rhodizonate. Nat. Energy 2, 861–868 (2017).

    Article Google Scholar

45. Ravel, B. & Newville, M. ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. J. Synchrotron Radiat. 12, 537–541 (2005).

    Article Google Scholar

46. Kresse, G. & Furthmuller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54, 11169–11186 (1996).

    Article Google Scholar

47. Perdew, J. P., Burke, K. & Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 77, 3865–3868 (1996).

    Article Google Scholar

48. Anisimov, V. I., Zaanen, J. & Andersen, O. K. Band theory and Mott insulators—Hubbard U instead of Stoner I. Phys. Rev. B 44, 943–954 (1991).

    Article Google Scholar

49. Xiao, P., Song, J., Wang, L., Goodenough, J. B. & Henkelman, G. Theoretical study of the structural evolution of a Na₂FeMn(CN)₆ cathode upon Na intercalation. Chem. Mater. 27, 3763–3768 (2015).

    Article Google Scholar

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